The rate constant of a chemical reaction is defined as the rate of the reacton when concentration of all reactants are unity, i.e., 1 mole / litre, for e.g., for a reaction,
A⟶ Products
Rate, R=k[A]
if [A]=1moll−1, then
k=R
where, k = Rate constant or proportionality constant.
The rate constant is the rate of the reaction when all the concentrations are set equal to unity.
The applications of rate law are :
(a) It can be used to estimate the rate of a reaction for any given composition of the reaction mixture.
(b) It can be used to predict the mechanism of a complex reaction.