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Question

1.0 g of magnesium is burnt with 0.56 g O2 in a closed vessel. Which reactant is left in excess and how much ? (At.wt. Mg=24; O=16)

A
Mg, 0.16 g
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B
O2, 0.16 g
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C
Mg, 0.44 g
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D
O2, 0.28 g
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Solution

The correct option is B Mg, 0.16 g
The reaction involved is:

2Mg+O22MgO

Now, No. of moles of Mg = 1.0g2.4g/mol=0.0416 moles
No. of moles of O2 = 0.56g32g/mol=0.0175 moles

1 mole O2 consumes 2 mole Mg & gives 2 mole MgO

O2 here is limiting reagent as 0.0416 moles of Mg require 0.0208 mole of O2 but only 0.0175 moles of O2 given.

0.0175 moles O2 will consume 2×0.0175 moles of Mg

No. of moles of Mg consumed = 0.035 moles

Remaining moles of Mg=0.04160.035

=0.0066 moles of Mg

As we know, 1 mole of Mg=24g

0.0066 moles of Mg=24×0.006=0.1584g

Amount of Mg left in excess = 0.16g

Hence, option A is correct.

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