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2.Mechanism o...

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2.Mechanism of HVZ reaction . ( Named reaction of Carboxylic Acid ).

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Q. Assertion :During

H V Z

reaction of a carboxylic acid, an alpha hydrogen of acid is replaced by halogen. Reason:

R C H X C O X

formed in the intermediate step supplies X to

R C H_{2} C O O H

.

Q. Question 33
A compound

X

is formed by the reaction of a carboxylic acid

C_{2} H_{4} O_{2}

and an alcohol in presence of a few drops of

H_{2} {SO}_{4}

. The alcohol on oxidation with alkaline

{KMnO}_{4}

followed by acidification gives the same carboxylic acid as used in this reaction. Give the names and structures of (a) carboxylic acid, (b) alcohol and (c) the compound

X

. Also write the reaction.

Q. Carboxylic acid doesnot give reactions of carbonyl group?

α

halogenation of aliphatic acids (HVZ reaction), the catalyst used is :

Q. The reaction of alcohols and carboxylic acids is called:

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