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Standard XII
Chemistry
Rate of Reaction
20. A: Two mo...
Question
20. A: Two moles of Grignard reagent is consumed in the formation of tertiary alcohol from ester followed by hydrolysis. R: One mole of Grignard reagent convert ester into Ketone and second mole of Grignard reagent adds to Ketone.
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Q.
Ketone reacts with Grignard reagent to produce tertiary alcohol via which of the following mechanism?
Q.
To convert a secondary alcohol into higher tertiary alcohol by Grignard reagent, the intermediate product is:
Q.
Which of these methods would serve to prepare 1-Phenyl-2-propanol?
a.
Addition of benzyl Grignard reagent to acetaldehyde (ethanal)
,
followed by hydrolysis.
b.
Addition of phenyl lithium to propylene oxide (methyloxirane)
,
followed by hydrolysis.
c.
Addition of phenyl Grignard reagent to acetone (2- propanone)
followed by hydrolysis.
d.
Acid- catalysed hydration (addition of water to) of 2-Phenyl-1-
propene.
e.
Addition of methyl Grignard reagent to acetophenone (methyl phenyl
ketone), followed by hydrolysis.
f.
Addition of methyl Grignard reagent to phenylacetaldehyde, followed
by hydrolysis.
Q.
Show how are the following alcohols prepared by the reaction of a suitable
Grignard reagent and aldehyde/ketone?
Q.
Which of the following compounds gives a ketone with grignard reagent?
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