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Nomenclature of Coordination Compounds

21. Compound ...

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21. Compound on reaction with H2/Pd-BaSO4(one equivalent) give A → Na/NH3(l)(B) B is

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Q. An organic compound

A

C_{7} H_{5} O C l

) on reaction with

H_{2} / P d

B a S O_{4}

B

B

undergoes disproportionation with

N a O H

C

D

B

on reaction with

C H_{3} M g B r / H_{3} O^{+}

E

. Identify the compounds and write their names.

Q. An organic compound

A (C_{4} H_{9} C l)

on reaction with

N a / d i e t h y l e t h e r

gives a hydrocarbon which on monochlorination gives only one chloro derivative.

A

Q. An organic compound A has molecular formula

C_{8} H_{12}

and is optically active It reacts with

H_{2} / P t

B (C_{8} H_{18})

which is optically inactive Careful hydrogenation of A with

P d / B a S O_{4}

C (C_{8} H_{14})

which is still optically active Compound A reacts with Na in liquid ammonia to give Diastereomer of C, but it is optically inactive Deduce structures of A to D.

Q. An organic compound (A)

[C_{4} H_{9} C l]

on reaction with

N a / e t h e r

gives a hydrocarbon which on monochlorination gives only one chloro derivative. Then (A) is:

Q. Compound (A) produces

C O_{2}

N a H C O_{3}

. Compound (A) also produces

H_{2}

gas with metallic Na. Further, compound (A) gives a positive iodoform test. Structure of (A) is:

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