34. Which of the following alkane upon Di chlorination can give only two products? 1) CH3-CH2-CH3 2) CH4 3) C(CH3)4 4) cyclohexane

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An alkane with molecular formula $C_{6} H_{14}$ gives two monochloro alkanes on chlorination. What is the structure of alkane?

Q. Which is the most suitable reagent among the following to distinguish compound (3) from rest of the compounds?

1. C H_{3} - C \equiv C - C H_{3}

2. C H_{3} - C H_{2} - C H_{2} - C H_{3}

3. C H_{3} - C H_{2} C \equiv C H

4. C H_{3} - C H = C H_{2}

i) C H_{3} - C H_{2} - C H_{3} | C H - C H_{2} - O = C H_{2} - C H_{3}

i i) C H_{3} - C H_{2} - C H_{2} - O - C H_{3} | C | C H_{3} - C H_{3}

Give the major products that are formed by heating each of the following ethers with HI.

Q. Arrange the following alkanes in decreasing order of their heats of combustion.
(i)

C H_{3} - C H_{3} | C | C H_{3} - C H_{3} (N e o - p e n t a n e)

(ii)

C H_{3} - C H | C H_{3} - C H_{2} - C H_{3} (I s o - p e n t a n e)

(iii)

C H_{3} - C H_{2} - C H_{2} - C H_{2} - C H_{3} (n - p e n t a n e)

Name the functional groups present in the following compounds: [5 MARKS]

1. ${CH}_{3} - {CH}_{2} - {CH}_{2} - OH$
2. ${CH}_{3} - {CH}_{2} - {CH}_{2} - COOH$
3. ${CH}_{3} - {CH}_{2} - CHO$
4. ${CH}_{3} - CO - {CH}_{2} - {CH}_{3}$
5. ${CH}_{3} - {CH}_{2} - CO-OH$

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