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Standard XII
Chemistry
Amines as Bases
4-methylpheno...
Question
4-methylphenol +CHCl3\xrightarrow{NaOH}salicyaldihyde + quinone derivative 4-methoxyphenol+CHCl3\overset{NaOH}{→ product (no quinone derivative)why} why different products are formed when OMe is replaced by -Me
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Q.
Quinones are
Q.
At
p
H
=
2
,
E
Q
u
i
n
h
y
d
r
o
n
e
will be (
E
Q
u
i
n
h
y
d
r
o
n
e
=
1.30
V
)
[Assume that the concentration of hydroquinone and quinone is
1
M
]
Q
H
2
→
Q
+
2
H
+
+
2
e
−
, where
Q
H
2
and
Q
stand for hydroquinone and quinone respectively. (Given,
2.303
R
T
F
=
0.06
)
Q.
P
h
e
n
o
l
H
O
N
O
−
−−−
→
(
a
)
⇌
(b) Identify (a) nad (b)
Q.
The correct stability order of the following three quinones is ?
Q.
Which of the following is the major product formed during dinitration of
3-methylphenol
?
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