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Question

Among the following, choose the compounds that can react with PCl5 to give POCl3.

A
P4O10
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B
H2SO4
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C
H2O
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D
SO2
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Solution

The correct option is D SO2
PCl5 produces POCl3 with the following reagents
PCl5+SO2POCl3+SOCl2
PCl5+H2OPOCl3+2HCl
2PCl5+H2SO4SO2Cl2+2POCl3+2HCl
6PCl5+P4O1010POCl3

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