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Question

An element has a face-centred cubic (fcc) structure with a edge length of a. The distance between the centres of two nearest tetrahedral voids in the lattice is:

A
a2
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B
a
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C
2a
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D
32a
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Solution

The correct option is A a2
In cubic close packing, each unit cell has 8 tetrahedral voids.
Each body diagonals in a unit cell contains 2 tetrahedral voids.
Let B and C are the two tetrahedral voids and X is the distance between the centre of void B and the centre of atom at corner A as shown in figure.


We know, the distance along the body diagonal of a cube is 3 a
where,
a is the edge length of the cell.

If a cube is divided into 8 minicubes, one tetrahedral void is present at the centre of each minicube.

3 a=4X
X=3 a4
Here two yellow tetrahedral voids are joined with each other forming a smaller cube of edge length a2.


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