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Question

At a pressure of 760 torr and temperature of 273 K, the indicated volume of which system is not consistent with the observation

A
14 g of N2+8 g of O2 ;volume=22.4 L
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B
4 g of He+44 g of CO2 ;volume=44.8 L
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C
7 g of N2+36 g of O3 ;volume=22.4 L
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D
17 g of NH3+36.5 g of HCl ;volume=44.8 L
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Solution

The correct option is A 14 g of N2+8 g of O2 ;volume=22.4 L
Pressure P = 760 torr = 1 atm
T = 273 K
Total moles, n = 1428 + 832 = 0.75 mol
Using ideal gas equation, PV = nRT
V = nRTP = 0.75×0.0821×2731 = 16.8 L
So option (a) is inconsistent.
Rest all options are consistent.

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