At a pressure of 760 torr and temperature of 273K, the indicated volume of which system is not consistent with the observation
A
14g of N2+8g of O2;volume=22.4L
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B
4g of He+44g of CO2;volume=44.8L
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C
7g of N2+36g of O3;volume=22.4L
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D
17g of NH3+36.5g of HCl;volume=44.8L
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Solution
The correct option is A14g of N2+8g of O2;volume=22.4L Pressure P = 760 torr = 1 atm T = 273 K Total moles, n = 1428 + 832 = 0.75 mol Using ideal gas equation, PV = nRT V = nRTP = 0.75×0.0821×2731 = 16.8 L So option (a) is inconsistent. Rest all options are consistent.