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Monosaccharide

BCl 3, BBr 3 ...

Question

$B C l_{3}, B B r_{3} a n d B I_{3}$ undergo rapid and complete hydrolysis but the fluoride are not completely hydrolysed due to formation of –

A

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B

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C

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D

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Solution

The correct option is D

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Similar questions

The correct order of Lewis acidity of $B X_{3}$ molecule is

B F_{3}, B C l_{3}, B B r_{3}, B I_{3}

which has more acidic nature.

B F_{3} < B C l_{3} < B B r_{3} < B I_{3}

Above order is correct for

B F_{3}

undergoes in partial hydrolysis. Reason: Due to strong back bondig in

B F_{3}

only two fluoride groups have come out on nucleophilic attack by

H_{2} O

.

Q. Consider the following boron halides:
I.

B F_{3}

B C l_{3}

B B r_{3}

B I_{3}

The Lewis acid characters of these halides are such that:

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