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s and p Overlap

Bond angle in...

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Bond angle in SO2Cl2

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Q. In which of the following pair both species have same Cl-x-Cl bond angle?
•CCl₄, SiCl₄
•POCl₃ , SO₂Cl₂
•BCl₃ , AlCl₃
And why??

Q. The number of moles of

S O_{2} C l_{2}

13.5 g

Consider the molecules $C H_{4}$ , $N H_{3}$ and $H_{2} O$ . Which of the given statements is false?

Q. Assertion :Bond angle of

{P F}_{3} > P {C l}_{3}

but bond angle of

P {C l}_{3} < P {B r}_{3}

Reason: The bond angles show an increase on decreasing electronegativity of attached other atom on central atom but in

{P F}_{3}

p π - d π

bonding results in an increase in bond angle.

S O_{2} C l_{2 (g)} \to S O_{2 (g)} + C l_{2 (g)},

S O_{2} C l_{2}

changed from 5 atm to 4 atm in 10 min. Then, pressure of

S O_{2} C l_{2}

at the end of 30 minutes will be (in atm):

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