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Question

Calcium carbonate reacts with aqueous HCI to give CaCl2 according to the reaction,

CaCO3(s) + 2HCl (aq) Cacl2(aq)+ CO2(g) + H2O(l.)

What mass of CaCO3 is required to react completely with 25 mL of 0.75 M HCl?

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Solution

Calculation of amoun of HCl

0.75 M HCl means 0.75 mol of HCl are present in 1L of water.

We know that, molar mass of HCl = 36.5 g mol1

So, mass of HCl present in 1L of water

= (0.75 mol) × (36.5 g mol1 = 27.375 g.)

Thus,1000 mL of solution contains 27.375 g of HCl.

Therefore, mass of HCl present in 25 mL of solution.

= 27.375g1000mL × 25 mL

= 0.6844 g

Calculation of mass of CaCO3 required.
Given balanced chemical equation is:

CaCO3(s) + 2HCl(aq) CaCl2(aq) + CO2(g) H2O(l)

So,2 moles of HCl reacts with 1 mole of CaCO3

Hence,73 g of HCl reacts with 100 g of CaCO3

Therefore, amount of CaCO3 that is required to react with

0.6844 g of HCl

=10073 × 0.6844 g
= 0.9375 g

Final answer: Amount of CaCO3 that will react with 0.6844 g HCl according to balenced chemical equation = 0.9375 g.

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