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Question

Calculate E0 and E for the cell Sn|Sn2+(1M)||Pb2+(103M)|Pb,E0(Sn2+|Sn)=0.14VE0(Pb2+|Pb)=0.13V. Is cell representation correct?

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Solution

Snsn+21M//pb+2(103M)/pbE0(sn+2/sn)=0.14vE0(pb+2/pb)=0.13vSn+pb+2pb+Sn+2E0cel=E0cathodeE0anode=0.13(0.14)=0.01Ecel=E0cel0.059nlog(1)(1)103=0.010.0592log1000=0.010.0885=0.0785vHereEcelisnegativeSo,Representatiomiswrong

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