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Reactions of Aryl Amines (Diazo Salts)

CH3CONH2, Br2...

Question

$C H_{3} C O N H_{2}, B r_{2} and K O H$ give $C H_{3} N H_{2}$ as the product. The intermediates of the reaction are
The correct answer is:

A

a, c

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B

a, b

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C

b, d

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D

c, d

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Solution

The correct option is B a, b
In Hoffmann's bromamide degradation reaction.

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Similar questions

Q. In the Hofmann bromamide degradation reaction below

R C O N H_{2} + K O H + B r_{2} ⟶

the intermediates involved are

Q. In the reaction,

C H_{3} N H_{2} + X + K O H \to C H_{3} N C, X

Q. The product obtained in the reaction of

C H_{3} C O N H_{2}

N a N O_{2} / H C l

Q. Match the column I with column II and mark the appropriate choice.

	Column I		Column II
$(A)$	$C H_{3} N H_{2} + C H C l_{3} + K O H Δ - \to$	$(i)$	$C H_{3} N H_{2}$
$(B)$	$C H_{3} C O N H_{2} + B r_{2} + K O H \to$	$(i i)$	$C H_{3} O H$
$(C)$	$C H_{3} N H_{2} + N a N O_{2} + H C l \to$	$(i i i)$	$C H_{3} N H C H_{3}$
$(D)$	$C H_{3} N C + 4 H P t - \to$	$(i v)$	$C H_{3} N C$

Q. Reactants of reaction

- I

{C H}_{3} C O {N H}_{2}

K O H

{B r}_{2}

Reactants of reaction

- I I

{C H}_{3} {N H}_{2}

C H {C l}_{3}

A l c o h o l i c K O H

The intermediate species of reaction

- I

- I I

are respectively

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Reactions of Aryl Amines (Diazo Salts)

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