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Standard XII
Chemistry
Relating Translational KE and T
Derive Boyle'...
Question
Derive Boyle's law using kinetic theory of gases.
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Solution
According to Boyle's law at constant temperature pressure & volume of gas are related as
P
V
=
Constant
According to kinetic theory, pressure of gas is
P
=
1
3
r
V
2
Since
m
v
v
=
r
P
V
=
1
3
m
N
v
2
Multiplying & dividing by
2
on
R
H
S
P
V
=
2
3
N
(
1
2
m
V
2
)
1
2
m
V
2
=
K
.
E
.
P
V
=
2
3
N
K
.
E
.
= constant
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