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Question

Ethanol is dehydrated in three ways as shown above. Major products (A), (B) and (C) respectively are:

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A
C2H5HSO4, C2H5OC2H5, C2H4
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B
C2H4, C2H5OC2H5, C2H5HSO4
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C
C2H5HSO4, C2H4, C2H5OC2H5
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D
C2H4, C2H5HSO4, C2H5OC2H5
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Solution

The correct option is A C2H5HSO4, C2H5OC2H5, C2H4
At 383K, sulfuric acid reacts with ethanol to form ethyl hydrogen sullfate and water.
At 431K, in presence of sufluric acid, 2 molecules of ethanol gives one molecule of diethyl ether. Water is eliminated in the process.
At 443K, dehydration of ethanol in presence of sulfuric acid gives ethene.
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