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Base Catalysed Hydrolysis of Esters

find the acid...

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find the acidic strength 1) ch3-ch2-cooh 2) cooh-ch2-cooh 3) coo^--ch2-cooh 4) ch3-ch-ch3-ch2-cooh 5) ch3-c-ch3-ch3-ch2-coo

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Q. Examine the given structural formula and select the esters. You may also identify the chemical required for their preparation.
1.

C H_{3} - C H_{2} - C O O - C H_{3}

C H_{3} - C H_{2} - C O O H

C H_{3} - C H_{2} - C O - C H_{3}

C H_{3} - O H

C H_{3} - C H_{2} - C H_{2} O H

C H_{3} - C O O H

C H_{3} - C O O - C H_{2} - C H_{2} - C H_{3}

Q. Identify the type of the following reaction of carbon compounds.
a. CH₃ -CH₂ -CH₂-OH → CH₃ -CH₂ -COOH
b. CH₃ -CH₂ -CH₃ → 3CO₂ + 4H₂O
c. CH₃ -CH = CH -CH₃ + Br₂ → CH₃ -CHBr - CHBr -CH₃
d. CH₃ -CH₃ + Cl₂→ CH₃ -CH₂ -Cl + HCl
e. CH₃-CH₂ -CH₂ -CH₂ -OH → CH₃ -CH₂ -CH=CH₂ + H₂O
f. CH₃-CH₂ -COOH + NaOH → CH₃ -CH₂ -COO - Na⁺ + H₂O
g. CH₃ -COOH + CH₃ -OH → CH₃ -COO- CH₃ + H₂O

Q. Find out the order of stability between

(A) C H_{3} - C H_{2} - C | C O O H H - - C H - C H_{3}

(B) C H_{3} - C | C O O H H - C H_{2} - - C H - C H_{3}

(C) C | C O O H H_{2} - C H_{2} - C H_{2} - - C H - C H_{3}

Q. Which is the stronger acid in each of the following pairs?
(i)

C H_{3} - C O O H

C H_{2} = C H - C O O H

C_{6} H_{5} - C O O H

C_{6} H_{5} - C H_{2} - C O O H

C H_{3} - C H_{2} - C O O H

C H_{3} - C H | O H - C O O H

Q. Write IUPAC names of the following

@CH3-CH2-CH=CH2
@CH3-CH2-CH2-C(CH3)2-CH3
@CH3-CH2-CHO
@CH3-CH(OH)-CH3
@CH3-CH2-CH2-COOH

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Base Catalysed Hydrolysis of Esters

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