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Question

For the reaction
C2H6C2H4+H2
the reaction enthalpy, ΔrH _____k J mol1.
[Round off to the Nearest Integer]
[Given : Bond enthalpies in kJmol1
C - C : 347, C = C : 611;
C - H : 414, H - H : 436]

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Solution

C2H6C2H4+H2

ΔrH=Sum of bond dissociation energy - Sum of bond formation energy
ΔrH=(B.E)CC+6×(B.E)CH[(B.E)C=C+4×(B.E)CH+(B.E)HH]

ΔrH=347+6×414(611+4×414+436)
ΔrH=28312703
ΔrH=128 kJ mol1


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