wiz-icon
MyQuestionIcon
MyQuestionIcon
1
You visited us 1 times! Enjoying our articles? Unlock Full Access!
Question

For thiocyanate ion (SCN−), three resonating structures are possible with the electron-dot method as shown below:

The decreasing order of % contribution to the resonance hybrid is:

A
a>b>c
Right on! Give the BNAT exam to get a 100% scholarship for BYJUS courses
B
a>c>b
No worries! We‘ve got your back. Try BYJU‘S free classes today!
C
c>b>a
No worries! We‘ve got your back. Try BYJU‘S free classes today!
D
Cannot be predicted
No worries! We‘ve got your back. Try BYJU‘S free classes today!
Open in App
Solution

The correct option is A a>b>c
Out of all the possible resonating structures, a more stable structure will contribute more to the resonance hybrid and the stability of any resonating structure can be discussed on the basis of its formal charge. Formal charges help in the selection of the most stable structure from all the possible structures.
Formal charge on any atom is calculated as:

Formal charge (FC) = V L B2
where,
V = Total number of valence electrons in an atom.
L = Total number of non-bonding (lone pair) electrons in an atom.
B = Total number of bonding (shared) electrons in that particular atom.

In structure (a),
Formal charges on S,C & N are 1,0,0

In structure (b), Formal charges on S,C & N are 0,0,1

Formal charges on

In structure (c).
Formal charges on S,C & N are 1,0,2

Out of the three, structure (c) is the most unstable because it has more formal charges when compared to the other two structures. Hence, it is considered to be less contributing. Also, even though N is more electronegative than S, a negative charge on N is more unstable because it has a smaller size than S.
Therefore most contributing resonance structure is (a) , where the negative charge is present at the S end.
correct order is : a>b>c

flag
Suggest Corrections
thumbs-up
9
Join BYJU'S Learning Program
similar_icon
Related Videos
thumbnail
lock
Mesomeric Effect
CHEMISTRY
Watch in App
Join BYJU'S Learning Program
CrossIcon