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Question

Given that 12S8(s)+6O2(g)4SO3(g);ΔH0=1590kJ. The standard enthalpy of formation of SO3 is:

A
1590 KJ mol1
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B
397.5 KJ mol1
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C
3.975 KJ mol1
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D
+397.5 KJ mol1
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Solution

The correct option is C 397.5 KJ mol1
Solution:- (B) 397.5kJ/mol
Given:-
12S8(s)+6O2(g)4SO3(g);ΔH=1590kJ.....(1)
As we know that the enthalpy of formation of a product is equal to the enthalpy of reaction when one mole of product is formed from its constituent elements.
Thus, dividing eqn(1) by 4, we have
14×[12S8(s)+6O2(g)4SO3(g);ΔH=1590kJ]
18S8(s)+32O2(g)SO3(g);ΔH=397.5kJ
Hence the enthalpy of formation of SO3(g) is 397.5kJ.

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