Given that E0 values of Ag+/Ag,K+/K,Mg2+/Mg and Cr3+/Cr are 0.80V,−2.90V,−2.37V and −0.74V respectively. Which of the following orders regarding the reducing power of the metals is correct?
A
Ag>Cr>Mg>K
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B
Ag<Cr<Mg<K
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C
Ag>Cr>K>Mg
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D
Cr>Ag>Mg>K
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Solution
The correct option is BAg<Cr<Mg<K More positive reduction potential means more easily an ion is reducible and more difficult is the oxidation of the corresponding atom. Reducing power of the metal means more easily the metals should be oxidisable. So, lesser the value of reduction potential, more is the reducing power. Hence Ag(0.80V) has least reducing power whereas K(−2.90V) with least reduction potential has maximum reducing power.
Hence, (b) is correct.