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Question

How do the boiling point and melting point of hydrocarbons change with an increase in molecular mass?

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Solution

  • The boiling point and melting point of hydrocarbon are directly related to molecular mass.
  • As the molecular mass of molecules increases, the Vandar Waals force between the molecules will increase.
  • Due to an increase in Vandar Waals's force of attraction, the boiling point and melting point of molecules increase.
  • Further among the hydrocarbons with same molar mass, the linear hydrocarbons will have more boiling points due to symmetry and can be packed effectively.


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