The structure of Diborane is formed by banana bonding. They are highly flammable, toxic and exothermic in nature.
The electronic configuration of B is indicates the atomic number is 5. In exited state, one of the valence electron get excited to and form hybridized orbitals. There are four hybrid orbitals one is empty and one has .
The B atom in has two covalent bond. Thus, 2B forms covalent bond. Now, two B left with one empty orbital and one unpaired electron in each B atom. The bridge is formed between . These bonds are known as Banana bonds with the involvement of three atoms and one electron from Hydrogen and other from Boron, two electrons. A system of 3 atoms and 2 electron is formed.