One molecule of Na3PO4contains 3 ions of Na+.
Molarity(M)=no.of moles(n)/Volume in litre (l)
⇒n=M×l=0.40M×0.02l=0.008moles One ion of Na+ contribute 0.008 mol
So total moles of Na+ = 0.008×3=0.024moles(answer)