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Question

How many nodes are present in 3s, 3p, and 3d orbitals?


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Solution

  1. Orbital nodes: They are regions where the phase of the quantum mechanical wave function (ψ) and ψ2 changes. At nodes, both ψ and ψ2 are zero because the phase is changing from positive to negative or vice versa.
  2. The electron density is 0 when ψ2 is zero. As a result, the electron density at a node is zero.
  3. Rule for number of nodes: Nodes are always one less than the principal quantum number = n - 1.
  4. n = 1 in the first electron shell. Thus, there are no nodes in the 1s orbital.
  5. n = 2 in the second electron shell. There is only one node in the 2s and 2p orbitals.
  6. n = 3 in the third electron shell. There are two nodes in the 3s, 3p, 3d orbitals.
  7. Hence, there are two nodes in the 3s, 3p, and 3d orbitals.

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