Multi-Electron Configurations and Orbital Diagrams
How many node...
Question
How many nodes are present in 3s, 3p, and 3d orbitals?
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Solution
Orbital nodes: They are regions where the phase of the quantum mechanical wave function () and changes. At nodes, both and are zero because the phase is changing from positive to negative or vice versa.
The electron density is 0 when is zero. As a result, the electron density at a node is zero.
Rule for number of nodes: Nodes are always one less than the principal quantum number = n - 1.
n = 1 in the first electron shell. Thus, there are no nodes in the 1s orbital.
n = 2 in the second electron shell. There is only one node in the 2s and 2p orbitals.
n = 3 in the third electron shell. There are two nodes in the 3s, 3p, 3d orbitals.
Hence, there are two nodes in the 3s, 3p, and 3d orbitals.