Since a and b are unit vectors, |a| = 1, |b| = 1
Lets assume angle between the unit vectors, a and b, is x.
Now, Using the law of cosines on the triangle formed by vector a, b and its resultant:
|a - b| = sqrt( |a|^2 + |b|^2 - 2 cosx)
=> |a - b| = sqrt( 1 + 1 - 2 cosx)
Since, cosx = 1 - 2 sin^2 (x/2)
=> |a - b| = sqrt( 2 - 2 + 4 sin^2 (x/2))
=> |a - b| = 2 sin(x/2)
=> sin(x/2) = 1/2 |a - b| Hence proved