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Polyhalides - Structures

Iodine trichl...

Question

Iodine trichloride exists as a dimer $I_{2} C l_{6},$ in solid state. Let, X = number of $3 c - 4 e^{-}$ bond, Y = maximum number of atoms in a plane and Z = number of $2 c - 2 e^{-}$ bond present in this molecule.Then find $(\frac{X \times Y}{Z})$

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Solution

$I_{2} C l_{6}$ contain $2, (3 c - 4 e^{-})$ bonds and $4, (2 c - 2 e^{-}) b o n d s$ .
It is a planar dimer. So, all the atoms are in plane.
Thus, $X = 2, Y = 8 a n d Z = 4$ .
Hence $\frac{X \times Y}{Z} = 4$

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