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Question

Markovnikov’s rule:

Alkenes undergo electrophilic addition reactions. They are triggered by the acid acting as an electrophile toward the π-electrons of the double bond.

Markovnikov’s rule states that when an unsymmetrically substituted alkene reacts with a hydrogen halide, the hydrogen atom adds to the carbon that has a greater number of hydrogens, e.g.,


Which given substrate is the most reactive toward Markovnikov’s addition?

A
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B
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C
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D
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Solution

The correct option is B
Presence of electron donating groups adjacent to the double bond increases the reactivity towards markonikov's addition.

Hence, (b) is the most reactive

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