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Formation of Enamines

Match Ligand ...

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Match Ligand Propertyate 1-ethylenediamine a-bident 2-hydrazene b-tridentate 3-dmg c-from hydrazenium ion on protonation 4-dien d-can form dimer

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Q. Total number of ligands which can act as bidentate / polydentate ligands with same donor atoms/sites.
DMG, en, Phen, Gly, acac,

S O_{4}^{2 -},

P P h_{3}

Q. Consider the following ligands

N H_{2}^{-}

, acac (Acetylacetone),

O H^{-}

O_{2}^{-}

N O_{2}^{-}, C O_{3}^{2 -}, C l^{-}, C H_{3} C O O^{-}, e n, S O_{4}^{2 -}, N_{2}^{-}

. Then calculate value of "

P + Q - R - S "

. Here
P: Total number of ligands which act as bridging as well as monodentate only.
Q: Total number of flexidentate ligands.
R: Total number of bidentate ligands only.
S: Total number of unsymmetrical bidentate ligands.

Q. Which of the following are bidentate monoanion ligands?
(1) Acetylacetonato
(2) Oxalato ion
(3) Dimethylglyoximato
Select the correct answer using the codes given below:

Q. The closed ring compounds formed by bidentate ligands, on binding to a metal or metal ions, are called:

Q. Which of the following molecules or ions may act as a bidentate ligand?

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Formation of Enamines

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