Since 20a3 is a 4-digit number and a multiple of 3.
So, the sum of all digits of 20a3 will be a multiple of 3.
2 + 0 + a + 3 = 5 + a
5 + a should be a multiple of 3.
If 5 + a = 3
⇒ a = -2
a is a digit of a number and it cannot be negative.
If 5 + a = 6
⇒ a = 1
If 5 + a = 9
⇒ a = 4
If 5 + a = 12
⇒ a = 7
If we take 5 + a = 15 ⇒ a = 10 which is a two digit number, but we already know that a is a single digit.
Therefore, possible values of a are 1, 4 and 7.
Required sum = 1 + 4 + 7 = 12