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Question

1.46 g of a biopolymer dissolved in a 100 mL water at 300 K exerted an osmotic pressure of 2.42×103 bar.

The molar mass of the biopolymer is x×104 g mol1 (Round off to the Nearest Integer)

[Use : R=0.083 L bar mol1K1]

A
15.00
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B
15
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C
15.0
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Solution

Osmotic pressure: (π)
π=i×C×R×T
Here
i is van't Hoff factorC is concentration (Molarity)R is ideal gas constant T is temperature

2.42×103=1×1.46×1000×0.083×300M×100

M=150223 g mol1

M=15.0223×104 g mol1x=15

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