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Question

Nitrogen can be estimated by Kjeldahl’s method for which of the following compound?


A
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B
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C
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D
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Solution

The correct option is D

Explanation for correct answer:-

Option (D)

  • Kjeldahl method is used in order to determine the Nitrogen content in the various organic and inorganic compounds.
  • But there are some limitations while using this method as some compounds are not suitable for this method.
  • Compounds that have nitrogen in the Azo or nitro group or the compounds where nitrogen is present in the ring(Pyridine, Quinoline) can't be detected by this method.
  • In this compound the Nitrogen is not directly attached to the Benzene ring, nor there is presence of an Azo or Nitro group.
  • Thus the Kjeldahl method is suitable for this compound.

Explanation for incorrect answer:-

Option (A)

  • This compound is Benzene diazonium chloride and here there is a presence of an Azo group.
  • Thus it is not suitable for the Kjeldahl method.
  • Hence it is the incorrect option.

Option (B)

  • This compound is Nitro benzene and here there is a presence of a nitro group.
  • Thus it is not suitable for the Kjeldahl method.
  • Hence it is the incorrect option.

Option (C)

  • This compound is Nitro benzene and here the Nitrogen is attached to the ring itself.
  • Thus it is not suitable for the Kjeldahl method.
  • Hence it is the incorrect option.

Therefore, Nitrogen can be estimated by Kjeldahl’s method for option (D)


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