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Mechanism of Carrier Conduction

NO2 present i...

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NO2 present in gaseous state, while N2O4 in solid state. The magnetic nature of NO2 & N2O4 arerespectively:(1) Paramagnetic, Diamagnetic(2) Both paramagnetic(3) Both diamagnetic(4) Diamagnetic, Paramagnetic

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Q. Assertion (A):

N O_{2}

is paramagnetic molecule, whereas

N_{2} O_{4}

is diamagnetic
Reason (R): Molecules with unpaired electrons are Diamagnetic.

Q. The magnetic nature of

[C r (N H_{3})_{6}]^{3 +} a n d [C o (N H_{3})_{6}]^{3 +}

Q. Of the following statements which are true for

N O_{2}

?

i)

Nitrogen dioxide brown liquid turns pale on cooling and becomes colourless solid
ii)

N O_{2}

undergoes dimerisation to form

N_{2} O_{4}

N O_{2}

is paramagnetic,

N_{2} O_{4}

[N i C l_{2} {P (C_{2} H_{5})_{2} (C_{6} H_{5})}_{2}]

exhibits temperature dependent magnetic behavior (paramagnetic/diamagnetic). The coordination geometries of

N i^{2 +}

in the paramagnetic and diamagnetic states are respectively:

[N i C l_{2} {P (C_{2} H_{5})_{2} (C_{6} H_{5})}_{2}]

exhibits temperature dependent magnetic behaviour (paramagnetic/diamagnetic). The coordination geometry of

N i^{2 +}

in the paramagnetic and diamagnetic states are respectively:

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