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Question

Show how each of the following compound can be converted to benzoic acid?

A: Ethylbenzene

B: Acetophenone

C: Bromobenzene

D: Phenylenthene(Styrene)

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Solution

A:

Strong oxidising agents like potassium permanganate in the presence of KOH followed by protonation gives benzoic acid.


B:

Strong oxidising agents like potassium permanganate in the presence of KOH followed by protonation gives benzoic acid.


C:

Grignard reagents generally reacts with dry ice (solid CO2) and followed by an aqueous solution of acid work-up produce carboxylic acids.
The reaction can be given below-

D:

Phenylethene (Styrene) on strong oxidation with potassium permanganate (KMnO4) in the presence of strong alkali KOH convert alkenes into carboxylic acids.
The reaction can be given below-

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