Brewster found experimentally that the reflected and refracted rays are at right angles to each other, when light is incident at polarising angle. ∴ip+90o+r=180o r=90o−ip From Snell's law, sinisinr=μ ∴sinipsin(90−ip)=μ sinipcosip=μ (or) μ=tanip Tangent of the polarising angle is numerically equal to the refractive index of the medium.