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Nucleic Acids

THE CORRECT I...

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THE CORRECT INCREASING ORDER OF H-M-H BOND ANGLE IN NH3 , PH3 , SBH3 , BiH3 is--------

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N H_{3}, P H_{3}, A s H_{3}, S b H_{3}

in increasing bond angle.

Q. Arrange the following in the increasing order of their basic character:

N H_{3}, P H_{3}, A S H_{3}, S b H_{3}, B i H_{3}

Q. Which of the following orders is/are correct?

1. S b H_{3} > N H_{3} > A s H_{3} > P H_{3}

(Boiling point)

2. N H_{3} > P H_{3} > A s H_{3} > S b H_{3}

(Thermal stability)

3. N H_{3} > P H_{3} > A s H_{3} > S b H_{3}

(Basic character)

4. N H_{3} > P H_{3} > A s H_{3} > S b H_{3}

Q. Arrange the following in order of property indicated for each set:
a.

F_{2}, C l_{2}, B r_{2}, I_{2}

- increasing bond dissociation enthalpy.
b.

H F, H C l, H B r, H I

- increasing acid strength.
c.

N H_{3}, P H_{3}, A s H_{3}, S b H_{3}, B i H_{3}

- increasing base strength.

Q. Assertion: The boiling point order of group

15

P H_{3} < A s H_{3} < N H_{3} < S b H_{3} < B i H_{3}

H

N H_{3}

dominates van der Waals forces in bigger

S b

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