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Byju's Answer
Standard XII
Chemistry
Standard Electrode Potentials
The pKsp of...
Question
The
p
K
s
p
of
A
g
I
is 16.07. If the
E
∘
value for
A
g
+
|
A
g
is 0.7991 V. find the
E
∘
for the half cell recation
A
g
I
/
(
s
)
+
e
−
→
A
g
+
I
Open in App
Solution
A
g
I
(
s
)
⟶
A
g
+
+
I
−
K
s
p
=
[
A
g
+
]
[
I
−
]
At cathode:
A
g
I
+
e
−
⟶
A
g
+
I
−
E
o
R
e
d
=
?
Anode:
A
g
⟶
A
g
+
+
e
−
E
o
O
x
i
d
e
=
0.7991
V
E
c
e
l
l
=
E
o
c
e
l
l
−
0.0591
n
log
X
⇒
E
o
c
e
l
l
=
+
0.0591
n
log
K
s
p
[
E
c
e
l
l
=
0
]
⇒
E
o
c
e
l
l
=
−
0.0591
n
p
K
s
p
[
log
K
s
p
=
P
K
s
p
]
=
−
0.0591
1
×
(
16.07
)
=
−
0.949
V
.
E
o
c
e
l
l
=
E
o
c
a
t
h
o
d
e
+
E
o
a
n
o
d
e
⇒
−
0.949
=
E
o
c
a
t
h
−
0.7991
E
o
c
a
t
h
o
d
e
=
−
0.2159
V
.
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Similar questions
Q.
The
p
K
s
p
of AgI is 16.07. If the
E
∘
value for
A
g
+
/
A
g
is 0.7991 V, If the
E
∘
for the half cell reaction
A
g
I
+
e
−
→
A
g
+
I
−
, in Volts is
149
×
10
−
x
, then what is the value of x?
Q.
Given the data
25
0
C
A
g
+
I
−
→
A
g
I
+
e
−
,
E
0
=
0.152
V
A
g
→
A
g
+
e
−
,
E
0
=
0.800
V
What is the value of
log
K
s
p
for AgI?
Q.
Given the data at
25
0
C
,
A
g
+
I
−
→
A
g
I
+
e
−
;
E
0
=
0.152
V
A
g
→
A
g
+
+
e
−
;
E
0
=
−
0.800
V
What is the value of log
K
s
p
for
A
g
I
?
(
G
i
v
e
n
:
2.303
R
T
/
F
=
0.059
V
)
Q.
Given the data at
25
o
C,
A
g
(
s
)
+
I
(
a
q
)
→
A
g
I
(
s
)
+
e
−
,
E
o
=
0.152
V
A
g
(
s
)
→
A
g
+
(
a
q
)
+
e
−
,
E
o
=
−
0.800
V
What is the value of log
K
s
p
for AgI?
(
W
h
e
r
e
K
s
p
=
solubility product
,
2.303
R
T
F
=
0.059
V
)
.
Q.
Calculate the solubility product constant of
A
g
I
from the following values of standard electrode potentials.
E
∘
A
g
+
/
A
g
=
0.80
v
o
l
t
and
E
∘
I
/
A
g
I
/
A
g
=
−
0.15
v
o
l
t
at
25
∘
C
.
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