In short, acids are proton donors and bases are proton acceptors.
Take the following reaction for example:
HCl+NH3⇋NH+4+Cl−
Hydrochloric acid (HCl) is the Brønsted-Lowry acid because it donates a hydrogen ion. Ammonia (NH3) is the Bronsted-Lowry base because it accepts the hydrogen ion.
Based on the reaction above, the ammonium ion
(NH+4)is the conjugate acid of the base ammonia and the chloride ion (Cl−) is the conjugate base of hydrochloric acid.
Here's a tip to let you know which substance is the conjugate acid and which substance is the conjugate base:
A conjugate base has one less (H+) proton than the acids you started with.
A conjugate acid has one moreH+ proton than the base you started with.
Here's a general depiction of conjugate acid-base pairs:
HA represents an acid
B represents a base
A−represents the conjugate base since this substance has one less proton than the acid, HA.
HB+represents the conjugate acid since this substance has one more proton than the base, B.