The potential difference between any two points is defined as the amount of work done in moving a unit charge from one point to another.
EMF is the maximum potential difference when a circuit is not connected.
Potential difference is the difference when a circuit is closed.
A potential difference is always lower than an EMF.
Because when charges flow in a circuit, some energy is spent in the flow of charge through the electrolyte of the cell.
EMF is defined as the work done on a unit charge
The formula for electrical potential difference
Where is the potential difference, is the work done, is a unit charge
The potential difference measured in volts is given by
Where is the potential difference, is current and is a resistance.
Potential difference and Emf relation:
where, is the potential difference, is the current, is the potential difference of the cell and is the lost voltage of the circuit ( Due to internal resistance of battery).