Answer
The carbon atom has sp hybridization; the O atoms have
sp2hybridization.
Explanation:
You must first draw the Lewis structure for
CO2According to VSEPR theory, we can use the steric number (SN) to determine the hybridization of an atom.
SN = number of lone pairs + number of atoms directly attached to the atom.
SN = 2 corresponds to sp hybridization.SN=3 corresponds to
sp2hybridization.We see that the C atom has SN = 2. It has no lone pairs, but it is attached to two other atoms.
It has sphybridization.
Each O atom has SN = 3. It has 2 lone pairs and is attached to 1 C atom.
Just as the carbon atom hybridized to form the best bonds, so do the oxygen atoms.
The valence electron configuration of O is
[He]2s22p4To accommodate the two lone pairs and the bonding pair, it will also form three equivalent
sp2 hybrid orbitals.
Two of the
sp2 orbitals contain lone pairs, while the remaining
sp2orbital and the unhybridized p orbital have one electron each.
We can see this arrangement in the C=O bond of formaldehyde, which is equivalent to the right-hand side of the O=C=O molecule.
There is a similar arrangement on the left side of the O=C=O molecule, but the
π bond is horizontal rather than vertical.