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Question

What makes an amine more basic?


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Solution

Amines (-NH2):

  • Amines are the compounds and functional groups that contain a basic Nitrogen (N) atom with a lone pair.
  • The electron-donating group increases and the electron-withdrawing groups decrease the basicity of an amine.
  • Thus, the stronger the ability of an amine to donate the electron pair, the more basic it will be.

For examples:

  • To further comprehend it, when an electron-donating group, such as an alkyl group -CH3, is connected to an amine, it becomes more basic.
    In the other approach, when an electron-withdrawing group is attached, basic nature decreases.
    An alkyl-substituted amine, for example, is more basic than an aryl amine.
23.1. Properties of amines | Organic Chemistry II

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