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Question

When 1 mole H2O(g) and 1 mole CO(g) are heated at 1000C in a closed vessel of 5 litre, it will found that 40% of H2O react at equilibrium according to H2O(g)+CO(g)H2(g)+CO2(g).

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Solution

H2O(g)+CO(g)H2(g)+CO2(g)
at t=0 1mole 1mole
at eqn, (1-0.4) (1-0.4) 0.4 0.4
The total mixture is contained in 5 litre vessel.
KC=0.45×0.450.65×0.65=0.44molL1

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