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Question

Which of the following alkenes will have the highest heat of combustion?

A
1
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B
2
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C
3
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D
All have equal value of heat of combustion.
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Solution

The correct option is A 1

Alkene 1 has one alpha hydrogen.
Alkene 2 has four alpha hydrogens.
Alkene 3 has five alpha hydrogens.
More the number of alpha hydrogens, more are the hyperconjugative structures and more is the stability of the alkene.
More the stability of alkene , lesser is the heat of combustion.
So, the least stable alkene , i.e. 1 will have the highest value of heat of combustion.

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