Which of the following is paramagnetic?
B2
To determine the magnetic nature of molecules, first we have to draw MO energy level diagrams of all the molecules.
Due to presence of two unpaired electron in B2 it is paramagnetic in nature.
Since there are no unpaired electrons in C2 it is diamagnetic.
Again, as you can see,since there are no unpaired electrons in N2 it is diamagnetic.
Now, from the diagram, we have to see whether unpaired electrons are present or not.
B2 ⟶ 2 unpaired electrons
C2 ⟶ No unpaired electrons
N2 ⟶ No unpaired electrons
F2 ⟶ No unpaired electrons
⇒ Unpaired electrons signifies paramagnetic nature.
⇒ Therefore B2 is paramagnetic.