Which one of the following complexes will have four different isomers?

[C o (e n)_{2} C l_{2}] C l

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[C o (e n) (N H_{3})_{2} C l_{2}] C l

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[C o (P P H_{3})_{2} (N H_{3}) C l] C l

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[C o (e n)_{3}] C l_{3}

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Solution

The correct option is B $[C o (e n) (N H_{3})_{2} C l_{2}] C l$
Complex $[C o (e n) (N H_{3})_{2} C l_{2}] C l |$ will have four different isomers.

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Which of the following will have optical isomers without having geometrical isomers?

[P t (P y) (N H_{3}) B r C l]