The correct option is C Galena
Froth floatation method is used to remove gangue from sulphide ores.
Galena (ZnS) is a sulphide ore.
Magnetite (Fe3O4) is an ore of iron. Malachine [Cu2CO3(OH)2] is an ore of copper and cassiterite (SnO2) is an ore of tin. Hence, only galena contains sulphide ion, thus it is best concentrated by froth floatation method.