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Question

Why are Mn2+ compounds more stable than Fe2+ towards oxidation to their +3 state?

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Solution

Mn2+=1s2,2s2p6,3s2p6d5 (half-filled d-orbital)
Fe2+=1s2,2s2p6,3s2p6d6

Mn2+ compounds are more stable due to half-filled d-orbitals. Fe2+ compounds are comparatively less stable as they have six electrons in their 3d-orbital. So, they tend to lose one electrons (form Fe3+) and get stable 3d5 configuration.


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