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Elastomer

why benzylic ...

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why benzylic free radicle is more stable than allyl.

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Q. The false statements among the following are:
I. A primary carbocation is less stable than a tertiary carbocation.
II. A cyclopropyl methyl carbocation is less stable than allyl carbocation.
III. A tertiary free radical is more stable than a primary free radical.
IV. Isopropyl carbanion is more stable than ethyl carbanion.

Q. Benzyl carbonation is more stable than ethyl carbocation.Justify.

Q. How many carbocations given below are more stable than sec. butyl carbocation?
T-butyl carbocation, Benzyl carbocation, Allyl carbocation, Cyclopropebyl cation, Tropylium cation, n-butyl carbocation, n-Propyl carbocation, cyclopropylmethyl carbocation :

p

-methyl benzyl carbocation (I) is more stable than benzyl carbocation (II). Reason: Heterovalent or no bond resonance.

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