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Question

Zn + HNO3 ------ Zn(NO3)2 + NO2 + H2O please balance this in method which you have thought . But not in trail method

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Solution

this is a redox reaction and you should start by writing the oxidation and reduction halves and balancing them. Zn goes from 0 to +2 and N goes from +5 to +4.. do you see that? (NO3) is -1.. O is -2.

Hence the oxidation state = +5+(3×2)=1

NO2 is neutral. O is -2, O2 is -4.

so N is +4) anyway

Zn0Zn+2+2e
N+5+1eN+4

now balance the electrons... multiply the bottom equation by 2

Zn0Zn+2+2e
2N+5+2e2N+4

add

now fill in counter ions

Zn+2HNO3Zn(NO3)2+2NO2

now fill in the remaining H2O and HNO3 and put a _ in front of them

Zn+HNO3+2HNO3Zn(NO3)2+2NO2+H2O

now fill in the _...

Zn+2HNO3+2HNO3Zn(NO3)2+2NO2+2H2O


let's check..

left side.. 1 zn, 4 H's, 4 N's, 12 O's
right side 1 Zn, 4H's, 4 N's, 12 O's
electrons. 1 Zn loses 2. 2 N's gain 2×1=2
all is well...

now simplify by adding nitric acid together and putting it in the order you wrote above...

Zn+2HNO3Zn(NO3)2+2NO2+2H2O


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